Built electron by electron · Z = 119 → 170

Element 168: the eighth closed shell

Starting from oganesson (118), I added one proton and one electron at a time and let each atom settle into its own lowest-energy arrangement. Nothing was assigned by a filling rule: every configuration below comes out of the calculation.

The build

119: last electron in 8s, gap 0.71 eV (open) zeck 89+21+8+1120: last electron in 6f, gap 0.19 eV (open) zeck 89+21+8+2120121: last electron in 7d, gap 0.28 eV (open) zeck 89+21+8+3122: last electron in 6f, gap 0.46 eV (open) zeck 89+21+8+3+1123: last electron in 5g, gap 1.27 eV (open) zeck 89+34124: last electron in 5g, gap 2.33 eV (open) zeck 89+34+1124125: last electron in 5g, gap 3.23 eV (open) zeck 89+34+2126: last electron in 7d, gap 0.07 eV (open) zeck 89+34+3127: last electron in 6f, gap 0.96 eV (open) zeck 89+34+3+1128: last electron in 5g, gap 4.68 eV (open) zeck 89+34+5128129: last electron in 7d, gap 0.17 eV (open) zeck 89+34+5+1130: last electron in 5g, gap 4.32 eV (odd) zeck 89+34+5+2131: last electron in 5g, gap 1.62 eV (open) zeck 89+34+8132: last electron in 5g, gap 7.90 eV (open) zeck 89+34+8+1132133: last electron in 7p, gap 10.71 eV (odd) zeck 89+34+8+2134: last electron in 7p, gap 9.83 eV (odd) zeck 89+34+8+3135: last electron in 7p, gap 9.04 eV (odd) zeck 89+34+8+3+1136: last electron in 7d, gap 0.95 eV (open) zeck 89+34+13136137: last electron in 6f, gap 14.90 eV (odd) zeck 89+34+13+1138: last electron in 6f, gap 1.35 eV (open) zeck 89+34+13+2139: last electron in 7d, gap 0.10 eV (open) zeck 89+34+13+3140: last electron in 7d, gap 0.44 eV (open) zeck 89+34+13+3+1140141: last electron in 7d, gap 0.30 eV (open) zeck 89+34+13+5142: last electron in 6f, gap 0.49 eV (open) zeck 89+34+13+5+1143: last electron in 6f, gap 0.57 eV (open) zeck 89+34+13+5+2144: last electron in 6f, gap 0.63 eV (open) zeck 144144145: last electron in 6f, gap 0.37 eV (open) zeck 144+1146: last electron in 6f, gap 0.99 eV (open) zeck 144+2147: last electron in 6f, gap 1.07 eV (open) zeck 144+3148: last electron in 6f, gap 1.52 eV (open) zeck 144+3+1148149: last electron in 6f, gap 1.03 eV (open) zeck 144+5150: last electron in 6f, gap 0.83 eV (open) zeck 144+5+1151: last electron in 8s, gap 1.45 eV (open) zeck 144+5+2152: last electron in 8s, gap 1.01 eV (sub) zeck 144+8152153: last electron in 7d, gap 1.98 eV (open) zeck 144+8+1154: last electron in 7d, gap 0.07 eV (open) zeck 144+8+2155: last electron in 7d, gap 0.16 eV (open) zeck 144+8+3156: last electron in 7d, gap 0.24 eV (open) zeck 144+8+3+1156157: last electron in 7d, gap 0.79 eV (open) zeck 144+13158: last electron in 7d, gap 1.35 eV (open) zeck 144+13+1159: last electron in 7d, gap 1.94 eV (open) zeck 144+13+2160: last electron in 7d, gap 2.53 eV (sub) zeck 144+13+3160161: last electron in 8s, gap 2.83 eV (open) zeck 144+13+3+1162: last electron in 8s, gap 3.31 eV (sub) zeck 144+13+5162163: last electron in 8p, gap 2.37 eV (open) zeck 144+13+5+1164: last electron in 8p, gap 3.21 eV (open) zeck 144+13+5+2164165: last electron in 8p, gap 4.03 eV (open) zeck 144+21166: last electron in 8p, gap 4.84 eV (open) zeck 144+21+1167: last electron in 8p, gap 5.64 eV (open) zeck 144+21+2168: last electron in 8p, gap 6.45 eV (noble) zeck 144+21+3168169: last electron in 9s, gap 0.53 eV (open) zeck 144+21+3+1170: last electron in 7f, gap 0.04 eV (open) zeck 144+21+5
8s5g6f7d8p9stall = noble · outlined = closed subshell · faded = calculation unsettled · ● = no 1 in Fibonacci code

Colour is the subshell that took the newest electron. From 163 to 168 the six 8p slots fill in order, and at 168 the atom closes with a gap of 6.45 eV. The electron after that, 169, has to start a new shell (9s). That is what a noble gas is. LIT (non-relativistic model)

Noble gases: energy to remove the outermost electron
21018365486118168ZeV to remove the outer electron

168 continues the downward line of the seven known noble gases: 15.4, 13.2, 10.1, 9.1, 8.1, 7.7, 7.2, then 6.9 eV. LIT (model)

Relativity: the innermost electron (Dirac equation)
−mc² : the floor of empty spaceZ 118: +0.5154 mc²Z 137: +0.2275 mc²Z 150: -0.1019 mc²Z 160: -0.4843 mc²Z 165: -0.7310 mc²Z 168: -0.8981 mc²Z 169: -0.9575 mc²168170+ : divedinnermost electron energy

As Z rises, the innermost electron sinks. At 168 it sits at −0.90 mc². At about Z ≈ 169.7 it drops below −mc², the floor of empty space: the vacuum near the nucleus can then produce electron–positron pairs on its own. LIT (one electron, finite nucleus, A = 2.5Z)

What it does

168 is the last noble gas before the vacuum gives way. The golden ruler predicted 168 (144 + 21 + 3, no 1 in its code). The shell rule 2⌈(k+1)/2⌉² predicted 168. The self-consistent build closes at 168. One or two protons further on, the void pushes back. AMBER as a reading

What the build cannot see

For the smallest reader. We built bigger and bigger atoms, one bead at a time. At bead 168 the atom's coat was perfectly buttoned up, like the famous quiet gases. Two beads later, the middle of the atom pulled so hard that empty space itself started to crack.

Record

build     Kohn–Sham, LDA exchange + PZ correlation, log grid 3000 pts, aufbau by computed levels
dirac     1s bisection by node count, uniform-sphere nucleus R = 1.2·A^(1/3) fm, A = 2.5Z
closures  2 10 18 36 54 86 118 → 168 (gap 6.45 eV); sub-closures 152 (8s²), 160 (7d¹⁰), 162 (8s²)
dive      E1s(168) = −0.898 mc², E1s(169) = −0.958 mc², 170 below −mc²